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Aquatic food chain: Otter (Lontra longicaudis), an exploratory research with mercury (Hg). 

The aim of this research was to evaluate the total mercury (Hg) concentrations in otters (L.longicaudis) from different locations. To reach for these goals otter feaces (spraints) were collected in July, 2004, January, 2005 and May, 2005 at Barra Bonita and Bariri reservoirs, SP. The spraints were used, not only to identify the animal food intake, but also to analyze the concentration of total Hg. In addition, fur samples from these reservoirs, as well as from the Piracicaba river, the Fundação Parque Zoológico de São Paulo (São Paulo Zoo), from two dead animals found in the State of Bahia, and from a fur originated from a mining area in the Crixas river, Goiás State were also analyzed. The results indicated that otter’s spraints collected at the Barra Bonita reservoir presented 100,52 ng.g-1 medium Hg contents, in January, and 177,45 ng.g-1 in May, 2005. At Bariri reservoir, the medium Hg concentrations were 55,97 ng.g-1 in July, 2004 and 243,2 ng.g-1 in May, 2005. Analyzing theses same samples, considering the food intake, a great amount of Cichlidae fish family, followed by the Serrasalmidae fish family were identified. It were observed that high total Hg concentration in spraints were associated with scale frequency of fishes from the Serrasalmidae family found in the spraints. The analyses of the fur collected in the Barra Bonita and Bariri reservoirs showed that Hg concentration varied from 0.02 to 1.02 μg.g-1; in Piracicaba river, the total concentration was of 0.55 μg.g-1; at the gold mining area located at rio Crixás presented medium levels of 7.25 μg.g-1 and samples fur from Bahia presented 8.56 μg.g-1medium levels. Both, otter feaces and fur samples were acid digested in a mixture of HNO3:H2SO4:HClO4, in an open system, being the sample detection made by atomic fluorescence specthrometry. Accuracy was assessed by two Certified Reference Materials, DORM-2 and BCR-414, with good recovery percentage in both cases.
 
Study site at Bariri Reserve, São Paulo state


Spraints were cleaned up in the field, eliminating the sand
grains adhere to the sample
 
  
period 03/2003 to 11/2005